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Voc Loss Theory
According to Shockley−Queisser limit theory:
Δ E1: Thermoldynamic Loss
Δ E2: Radiative Recombination
Δ E3: Non-radiative Recombination
Through the value of EL and EQE to get the bandgap (Eg) and calculate Voc Loss
But actually only EL EQE decide the Voc
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Δ E1: Thermodynamic, refers to bandgap and temperature
∅_BB : Blackbody radiation spectrum under T (temperature of solar cells)
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Δ E2: Radiative Recombination
∅_BB: refers to Blackbody radiation spectrum under T (temperature of solar cells)
Jsc: refers to the short-circuit density under AM1.5G light illumination
J0, rad: refers to the dark current of solar cell and the EQE shape under the lowest energy
Generally speaking, E2 value depends on EQE; however, usually the value of E2 is small.
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Δ E3: Non-radiative Recombination
Can be calculated by EL EQE, and here is the formula :